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Venture capitalists, corporations, private-equity firms, and more poured billions into private companies this year--a huge boon for titans like Facebook and Groupon. Here, the best of the rest starting 2012 with supersize bankrolls

A sort of Match.com for philanthropy pairs up industry executives who want to give back with non-profits who need their skills. People who reach a certain level of success often decide they want to give back.